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Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration
นักวิจัย : Li, Xiukai , Wu, Di , Lu, Ting , Yi, Guangshun , Su, Haibin , Zhang, Yugen
คำค้น : DRNTU::Science::Chemistry::Organic chemistry
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2557
อ้างอิง : Li, X., Wu, D., Lu, T., Yi, G., Su, H., & Zhang, Y. (2014). Highly Efficient Chemical Process To Convert Mucic Acid into Adipic Acid and DFT Studies of the Mechanism of the Rhenium-Catalyzed Deoxydehydration. Angewandte Chemie, 126(16), 4284-4288. , 0044-8249 , http://hdl.handle.net/10220/19641 , http://dx.doi.org/10.1002/ange.201310991
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Angewandte chemie
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

The production of bulk chemicals and fuels from renewable bio-based feedstocks is of significant importance for the sustainability of human society. Adipic acid, as one of the most-demanded drop-in chemicals from a bioresource, is used primarily for the large-volume production of nylon-6,6 polyamide. It is highly desirable to develop sustainable and environmentally friendly processes for the production of adipic acid from renewable feedstocks. However, currently there is no suitable bio-adipic acid synthesis process. Demonstrated herein is the highly efficient synthetic protocol for the conversion of mucic acid into adipic acid through the oxorhenium-complex-catalyzed deoxydehydration (DODH) reaction and subsequent Pt/C-catalyzed transfer hydrogenation. Quantitative yields (99 %) were achieved for the conversion of mucic acid into muconic acid and adipic acid either in separate sequences or in a one-step process.

บรรณานุกรม :
Li, Xiukai , Wu, Di , Lu, Ting , Yi, Guangshun , Su, Haibin , Zhang, Yugen . (2557). Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Li, Xiukai , Wu, Di , Lu, Ting , Yi, Guangshun , Su, Haibin , Zhang, Yugen . 2557. "Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Li, Xiukai , Wu, Di , Lu, Ting , Yi, Guangshun , Su, Haibin , Zhang, Yugen . "Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2557. Print.
Li, Xiukai , Wu, Di , Lu, Ting , Yi, Guangshun , Su, Haibin , Zhang, Yugen . Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2557.